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Presenter: Mohamed Matoug
Supervisor:

Date: Mon, November 6, 2017
Time: 11:00:00 - 00:00:00
Place: EOW 430

ABSTRACT

In this work, different optical techniques have been explored to study and characterize crude oil and its asphaltene. Crude oils are extremely complex fluids used to produce fuel for a wide range of applications. The characterization of this fluid is key for optimum operations in the oil and gas industry.

First, we demonstrate the application of gold nanorods to characterize a different set of crude oils. We utilize the high sensitivity of the localized surface plasmon resonance (LSPR) of the nanorods to the surrounding environment to measure the crude oil refractive index. We immobilized the nanorods on a glass substrate and took the measurement in a reflection configuration. The setup and the nanorods were calibrated using different fluids with known refractive index, and a sensitivity of 247 nm/RIU and a resolution of 0.013 RIU have been achieved. In addition to the simplicity of this approach, it has eliminated the absorption issue and made it possible to measure high optical density crude oils with typical Visible-NIR wavelengths. Surface-Enhanced Raman spectra (SERS) can also be measured. SERS can give extra useful information, especially to some application such as downhole fluid analysis, where confirmation of the hydrocarbons presence is necessary.

 In the second part of this work, we have used Terahertz time-domain spectroscopy (THz-TDS) to study the asphaltenes in three different crude oils. THz-TDS has a feature of measuring the amplitude and time delay and consequently the refractive index and absorption coefficient spectra simultaneously. Our approach was based on measuring the THz signal from neat crude oil samples and comparing it with the THz signal after removing the asphaltene from the oil samples (maltene). The results show that the difference in the time delay and the peak amplitude between the neat oil and the maltene have a linear relation with the asphaltene content. The refractive index spectra of the asphaltene show variation in the low THz frequencies and comparable spectra in the higher frequencies. The absorption of the asphaltene was mild and no distinctive absorption feature was observed except some narrow absorption peaks that we attributed to water molecules adsorbed on the asphaltene.